期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 3, 页码 466-467出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja067148o
关键词
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The conformation and functionalizability of 4-azidoproline containing polyprolines was studied. The conformational analyses demonstrate that the PPII helix is stabilized by (4R)Azp and destabilized by (4S)Azp. Functionalization of Azp containing polyprolines was accomplished efficiently in a differential fashion by click chemistry, rendering Azp containing polyprolines attractive molecular scaffolds.
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