期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 4, 页码 750-751出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja067346f
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A successful stereochemical reversal was achieved in AgOAc catalyzed [3+2] cycloaddition by the formation of hydrogen bonding between ligand and reactant. This strategy provides an efficient and convenient route to prepare both enantiomers of a chiral compound. DFT studies proposed a reasonable mechanism of the reversal of the enantioselectivity; hydrogen bonding changed the transition state. The strategy may provide some useful hints for ligand design.
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