期刊
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
卷 63, 期 -, 页码 M567-M568出版社
BLACKWELL PUBLISHING
DOI: 10.1107/S1600536807001699
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The title compound, [Au(C3H9P)(2)]PF6, a linear two-coordinate gold(I) complex with coordinated trimethylphosphine ligands and hexafluorophosphate as counter-ion, is isomorphous with [Ag(Me3P)(2)]PF6 and exhibits similar bond distances to [Au(Me3P)(2)]Cl, thus unconditionally substantiating previous comparisons and claims that the ionic radius of Au is smaller than that of Ag. The cation has mirror symmetry, so that the P-Au-P axis lies in this plane. Similarly, the anion has mirror symmetry, with the plane containing an F-P-F axis.
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