期刊
PROGRESS IN POLYMER SCIENCE
卷 32, 期 2, 页码 173-219出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.progpolymsci.2007.01.003
关键词
anionic polymerization; carbanions; mechanisms; ion-pairs; kinetics; history
We present a review on the present status of anionic polymerization of important non-polar and polar vinyl monomers. After presenting the historical background-the pre-Szwarc era-we discuss the mechanisms of this polymerization, in particular several types of carbanions, their ion-pairs and their aggregates occurring in the initiation and propagation of non-polar and polar monomers, including recent developments. Finally, we discuss some important scientific and industrial applications of anionic polymerization. (c) 2007 Elsevier Ltd. All rights reserved.
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