期刊
INORGANICA CHIMICA ACTA
卷 360, 期 2, 页码 691-694出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2006.07.083
关键词
ruthenium(III) carbonyl complex; EPR; cyclic voltammetry; X-ray single crystal
An unusual coordination mode of salicylaldehyde N-phenylthiosemicarbazone (H-2-Sal-Ptsc) ligand was observed in unusual ruthenium(Ill) carbonyl complex for the first time when it was reacted with [RuHCl(CO)(PPh3)(3)]. The EPR and electrochemical analysis conformed the formation of Ru(III) species. (c) 2006 Elsevier B.V. All rights reserved.
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