期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 47, 页码 15455-15459出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809115
关键词
alkenes; esters; photocatalysis; radicals; ylides
资金
- JSPS KAKENHI [15H05756, 16K05694]
- JST [ACT-C] [JPMJCR12Z9]
- JSPS
A convenient method for synthesizing elongated aliphatic esters from alkenes is reported. An (alkoxycarbonyl)methyl radical species is generated upon visible-light irradiation of an ester-stabilized phosphorus ylide in the presence of a photoredox catalyst. This radical species adds onto the carbon-carbon double bond of an alkene to produce an elongated aliphatic ester.
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