期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 40, 页码 13120-13124出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201807173
关键词
electrocatalysis; fluorine; carbon dioxide reduction; covalent organic frameworks; methane
资金
- 1000 Plan Professorship for Young Talents
- Hundred Talents Program of FuJian Province
- Fujian Science and Technology Key Project [2016H0043]
- National Natural Science Foundation of China [21703250, 21875253]
Developing cost-effective electrocatalysts for high-selectivity CO2 electroreduction remains challenging. We herein report a perfluorinated covalent triazine framework (CTF) electrocatalyst that displays very high selectivity in the electroreduction of CO2 to CH4 with a faradaic efficiency of 99.3% in aqueous electrolyte. Systematic characterization and electrochemical studies, in combination with density functional theory calculations, demonstrate that the presence of both nitrogen and fluorine in the CTF provides a unique pathway that is inaccessible with the individual components for CO2 electroreduction.
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