期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 41, 页码 13509-13513出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201807256
关键词
host-guest chemistry; single-ion magnets; spin crossover; spintronic devices
资金
- ERC [258060]
- Spanish MINECO [MAT2014-53961-R, MAT2017-86826-R, CTQ2015-68370-P]
- Avempace II Erasmus Mundus Action 2 program
- DOE Office of Science User Facility [DE-AC02-05CH11231]
Single functional molecules are regarded as future components of nanoscale spintronic devices. Supramolecular coordination chemistry provides unlimited resources to implement multiple functions to individual molecules. A novel coordination [Fe-2] helicate exhibiting spin-crossover is demonstrated to be ideally suited to encapsulate a [Cr(ox)(3)](3-) complex anion (ox = oxalate), unveiling for the first-time single ion slow relaxation of the magnetization for this metal. A possibility of tuning the dynamics of this relaxation as well as the performance of the Cr-III center as qubit arises from the observation that metastable high spin Fe-II centers from the host can be generated by irradiation with green light at low temperature.
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