期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 7, 页码 1880-1891出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809432
关键词
anion recognition; chalcogen bonding; chalcogens; noncovalent interactions; organocatalysis
资金
- European Research Council [638337]
- Deutsche Forschungsgemeinschaft (Cluster of Excellence RESOLV) [EXC 1069]
- Fonds der Chemischen Industrie
- European Research Council (ERC) [638337] Funding Source: European Research Council (ERC)
In the last few decades, unusual noncovalent interactions like anion-pi and halogen bonding have emerged as interesting alternatives to the ubiquitous hydrogen bonding in many research areas. This is also true, to a somewhat lesser extent, for chalcogen bonding, the noncovalent interaction involving Lewis acidic chalcogen centers. Herein, we aim to provide an overview on the use of chalcogen bonding in crystal engineering and in solution, with a focus on the recent developments concerning intermolecular chalcogen bonding in solution-phase applications. In the solid phase, chalcogen bonding has been used for the construction of nano-sized structures and the self-assembly of sophisticated self-complementary arrays. In solution, until very recently applications mostly focused on intramolecular interactions which stabilized the conformation of intermediates or reagents. In the last few years, intermolecular chalcogen bonding has increasingly also been exploited in solution, most notably in anion recognition and transport as well as in organic synthesis and organocatalysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据