期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 57, 期 43, 页码 14179-14183出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201809611
关键词
C-H activation; electrochemistry; iridium catalysis; Redox catalysts; selectivity
资金
- DFG (Gottfried-Wilhelm-Leibniz award)
Iridium-catalyzed electrochemical C-H activation was accomplished within a cooperative catalysis manifold, setting the stage for electrooxidative C-H alkenylations through weak O-coordination. The iridium-electrocatalyzed C-H activation featured high functional-group tolerance through assistance of a metal-free redox mediator through indirect electrolysis. Detailed mechanistic insights provided strong support for an organometallic C-H cleavage and a synergistic iridium(III/I)/redox catalyst regime, enabling the use of sustainable electricity as the terminal oxidant with improved selectivity features.
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