3.8 Article

Palladium-catalysed aminocarbonylation of 17-iodo-5α-androst-16-ene with L-amino acid esters in ionic liquids

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REACTION KINETICS AND CATALYSIS LETTERS
卷 90, 期 1, 页码 159-165

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SPRINGER
DOI: 10.1007/s11144-007-5059-7

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carbonylation; ionic liquids; steroids; amino acid

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Ionic liquids were effectively used as solvents in palladium catalysed aminocarbonylation of 17-iodo-5 alpha-androst-16-ene (1) with L-amino acid esters. The Pd(OAc)(2) + phosphine catalysts could be recirculated with small loss of activity.

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