期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 33, 页码 8677-8681出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402449
关键词
C-H activation; copper; dearomatization; ligand design; synthetic methods
资金
- National Institutes of Health [GM46059]
A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives. A copper-catalyzed cyanative dearomatization mechanism is proposed to account for the regiochemical course of this reaction.
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