期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 13, 页码 3466-3469出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309967
关键词
asymmetric catalysis; CH functionalization; chirality; cross-coupling; organoiodine
资金
- NSFC [21232007, 21072181]
- MOST (973 project) [2010CB833300]
- Ministry of Education
An asymmetric organocatalytic direct CH/CH oxidative coupling reaction of N-1,N-3-diphenylmalonamides has been well established by using chiral organoiodine compounds as catalysts, wherein four CH bonds were stereoselectively functionalized to give structurally diverse spirooxindoles with high levels of enantioselectivity. More importantly, the findings indicated that chiral hypervalent organoiodine reagents can serve as alternative catalysts for the creation of enantioselective functionalization of inactive CH bonds.
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