期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 51, 页码 14206-14210出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408664
关键词
amine formation; dinitrogen conversion; dinitrogen reduction; Mo complexes; silicon radicals
资金
- Region Midi Pyrenees
- CNRS
- Region Midi-Pyrenees
Stoichiometric reduction of N-2 at a Mo center stabilized by a bulky tetradentate phosphine ligand (PP3Cy) allowed isolation of Mo-imidoamine and Mo-imido complexes. Both complexes as well as the Mo-II precursor are equally suitable catalysts for the synthesis of NTMS3 (TMS-trimethylsilyl) from N-2, TMSCl, and electron sources. Mechanistic studies prove the involvement of a TMS radical at least in one of the catalytic steps.
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