期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 2, 页码 430-+出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408862
关键词
metal-organic frameworks; oxidation; photochromism; sensitizers; singlet oxygen
资金
- Office of Naval Research [N000141310753]
- Center for Gas Separations Relevant to Clean Energy Technologies, an Energy Frontier Research Center - U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences [DE-SC0001015]
The controlled generation of singlet oxygen is of great interest owing to its potential applications including industrial wastewater treatment, photochemistry, and photodynamic therapy. Two photochromic metal-organic frameworks, PC-PCN and SO-PCN, have been developed. A photochromic reaction has been successfully realized in PC-PCN while maintaining its single crystallinity. In particular, as a solid-state material which inherently integrates the photochromic switch and photosensitizer, SO-PCN has demonstrated reversible control of O-1(2) generation. Additionally, SO-PCN shows catalytic activity towards photooxidation of 1,5-dihydroxynaphthalene.
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