期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 51, 页码 14022-14026出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404029
关键词
(4+1) cycloaddition; carbenes; cyclobutenes; gold catalysis; methylenecyclopropanes
资金
- European Research Council [321066]
- MINECO [CTQ2010-16088/BQU]
- EU Project ICT (ATMOL) [FP7-270028]
- ICIQ Foundation
- European Research Council (ERC) [321066] Funding Source: European Research Council (ERC)
7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C-1 component of the cycloaddition.
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