期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 35, 页码 9372-9375出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404032
关键词
bond order; carbenes; gold; homogeneous catalysis; intermediates
资金
- Universitat Heidelberg
- DFG
Gold-carbene complexes are essential intermediates in many gold-catalyzed organic-synthetic transformations. While gold-carbene complexes with direct, vinylogous, or phenylogous heteroatom substitution have been synthesized and characterized, the observation in the condensed phase of electronically non-stabilized gold-carbenes has so far remained elusive. The sterically extremely shielded, emerald-green complex [IPr**Au=CMes(2)](+)[NTf2](-) has now been synthesized, isolated, and fully characterized. Its absorption maximum at 642 nm, in contrast to 528 nm of the red-purple carbocation [Mes(2)CH](+), clearly demonstrates that gold is more than just a soft proton.
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