期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 13, 页码 3475-3479出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310275
关键词
alkenes; carboboration; copper; cross-coupling; synthetic methods
资金
- Indiana University
- Tsinghua University
Copper-catalyzed Suzuki-Miyaura-type cross-coupling and carboboration processes are reported. The cross-couplings function well with a variety of substituted aryl iodides and aryl boronic esters and allows for orthogonal reactivity compared to palladium-catalyzed processes. The carboboration method includes both alkynes and allenes and provides access to highly substituted and stereodefined vinyl boronic esters. The alkyne carboboration method is highlighted in the simple one-pot synthesis of Tamoxifen.
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