期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 14, 页码 3622-3625出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310939
关键词
electron transfer; fluorescence; molecular devices; molecular switches; triodes
资金
- Department of Employment and Learning, Northern Ireland
- Engineering and Physical Sciences Research Council (UK)
- IAESTE
The fluorophore-spacer(1)-receptor(1)-spacer(2)-receptor(2) system (where receptor(2) alone is photoredox-inactive) shows ionically tunable proton-induced fluorescence off-on switching, which is reminiscent of thermionic triode behavior. This also represents a new extension to modular switch systems based on photoinduced electron transfer (PET) towards the emulation of analogue electronic devices.
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