期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 25, 页码 6538-6541出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403693
关键词
carbene ligands; hydrodefluorination; hydrosilylation; Lewis acids; phosphonium salts
资金
- NSERC of Canada
- Canada Research Chair
- Alexander von Humboldt Foundation
The dicationic imidazolium-phosphonium salt [(SIMes) PFPh2][B(C6F5)(4)](2) has been prepared and shown to exhibit remarkable Lewis acidity in stoichiometric reactions and acting as an effective Lewis acid catalyst for the hydrodefluorination of fluoroalkanes and the hydrosilylation of olefins.
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