期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 12, 页码 3134-3137出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310679
关键词
aggregation; mesoporous materials; nanoparticles; Prussian blue; sodium-ion batteries
资金
- U.S. Department of Energy's Office of Basic Energy Science, Division of Materials Sciences and Engineering under UT-Battelle, LLC
The synthesis of mesoporous Prussian blue analogues through a template-free methodology and the application of these mesoporous materials as high-performance cathode materials in sodium-ion batteries is presented. Crystalline mesostructures were produced through a synergistically coupled nanocrystal formation and aggregation mechanism. As cathodes for sodium-ion batteries, the Prussian blue analogues all show a reversible capacity of 65mAhg(-1) at low current rate and show excellent cycle stability. The reported method stands as an environmentally friendly and low-cost alternative to hard or soft templating for the fabrication of mesoporous materials.
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