期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 47, 页码 12803-12807出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407917
关键词
anode materials; hollow nanostructures; lithium-ion batteries; nanobowls; SnO2
资金
- National Natural Science Foundation of China [51273158, 21303131]
- Natural Science Basis Research Plan in Shaanxi Province of China [2012JQ6003, 2013KJXX-49]
- Ministry of Education (Singapore) through the Academic Research Fund (AcRF) Tier-1 grant [RG12/13, M4011154]
Despite the great advantages of hollow structures as electrodes for lithium-ion batteries, one apparent common drawback which is often criticized is their compromised volumetric energy density due to the introduced hollow interior. Here, we design and synthesize bowl-like SnO2@carbon hollow particles to reduce the excessive hollow interior space while retaining the general advantages of hollow structures. As a result, the tap density can be increased about 30%. The as-prepared bowl-like SnO2@carbon hollow particles with conformal carbon support exhibit excellent lithium storage properties in terms of high capacity, stable cyclability and excellent rate capability.
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