期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 32, 页码 8388-8391出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404186
关键词
copper; gels; luminescence; polymers; self-assembly
资金
- European Research Council
- Middle East Technical University & Turkish Council of Higher Education
- Schlumberger-Faculty for the Future Fellowship program
- EPSRC [EP/K039520/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039520/1] Funding Source: researchfish
A dynamic-covalent metal-containing polymer was synthesized by the condensation of linear diamine and dialdehyde subcomponents around copper(I) templates in the presence of bidentate phosphine ligands. In solution, the red polymers undergo a sol-gel transition upon heating to form a yellow gel, a process that can be either reversible or irreversible depending on the solvent used. When fabricated into a light-emitting electrochemical cell (LEC), the polymer emits infrared light at low voltage. As the voltage is increased, a blue shift in the emission wavelength is observed until yellow light is emitted, a process which is gradually reversed over time upon lowering the voltage. The mechanism underlying these apparently disparate responses is deduced to be due to loss of the copper phosphine complex from the polymer.
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