期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 49, 页码 13573-13577出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408355
关键词
alkyl radicals; C-H activation; single electron transfer; heterocycles; palladium
资金
- Singapore Singapore Ministry of Education Academic Research Funding [MOE2013-T2-2-057]
- Nanyang Technological University
- Region Bourgogne
- CNRS
A general alkylation of heterocycles using a simple palladium catalyst is reported. Most classes of heterocycles, including indoles and pyridines, efficiently coupled with unactivated secondary and tertiary alkyl halides. An alkyl radical addition to neutral heteroarenes is most likely involved.
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