期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 50, 页码 13898-13901出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408380
关键词
dual catalysis; stereodivergent synthesis; tetrahydrocannabinol; total synthesis
资金
- ETH Zurich
- Swiss National Science Foundation [200020_152898]
- Swiss Commission for Technology and Innovation (CTI) [15175.1 PFLS-LS]
All four stereoisomers of (9)-tetrahydrocannabinol ((9)-THC) were synthesized in concise fashion using stereodivergent dual catalysis. Thus, following identical synthetic sequences and applying identical reaction conditions to the same set of starting materials, selective access to the four stereoisomers of THC was achieved in five steps.
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