期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 17, 页码 4460-4464出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310402
关键词
electrochemistry; in situ imaging; lithium-ion batteries; nanotomography; transmission X-ray microscopy
资金
- Laboratory Directed Research and Development (LDRD) project at Brookhaven National Laboratory
- U.S. Department of Energy, Office of Basic Energy Science [DE-AC02-98CH10886]
The three-dimensional quantitative analysis and nanometer-scale visualization of the microstructural evolutions of a tin electrode in a lithium-ion battery during cycling is described. Newly developed synchrotron X-ray nanotomography provided an invaluable tool. Severe microstructural changes occur during the first delithiation and the subsequent second lithiation, after which the particles reach a structural equilibrium with no further significant morphological changes. This reveals that initial delithiation and subsequent lithiation play a dominant role in the structural instability that yields mechanical degradation. This insitu 3D quantitative analysis and visualization of the microstructural evolution on the nanometer scale by synchrotron X-ray nanotomography should contribute to our understanding of energy materials and improve their synthetic processing.
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