期刊
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
卷 20, 期 2, 页码 109-114出版社
WILEY
DOI: 10.1002/poc.1131
关键词
high pressure; ionic liquids; Diels-Alder reaction; fluorous effect; Lewis acid catalysts
The effect of pressure on the Diels-Alder reaction was examined in room temperature ionic liquids, followed by high-pressure FT-IR spectroscopy using pressures up to 150MPa. Pressure enhances the kinetic sensitivity of the reaction. The-kinetic effect of fluorophobic interactions was examined using ionic liquids with fluorous cations. Ionic liquids in combination with ZnI2 as a Lewis acid catalyst were also studied under high pressure. Copyright (C) 2007 John Wiley & Sons, Ltd.
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