期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 24, 页码 6090-6094出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402192
关键词
cycloaddition; noncovalent interactions; platinum; polymers; supramolecular chemistry
资金
- National Natural Science Foundation of China [21274139, 91227119]
- Fundamental Research Funds for the Central Universities [WK2060200012]
- Anhui Provincial Natural Science Foundation [1208085QB22]
Supramolecular polymers are constructed based on the novel bis[alkynylplatinum(II)] terpyridine molecular tweezer/pyrene recognition motif. Successive addition of anthracene as the diene and cyano-functionalized dienophile triggers the reversible supramolecular polymerization process, thus advancing the concept of utilizing Diels-Alder chemistry to access stimuli-responsive materials in compartmentalized systems.
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