期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 45, 页码 12081-12085出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406911
关键词
heterogeneous catalysis; metal hydrides; polymers; sensors; thin films
资金
- Netherlands Organisation for Scientific Research
- NanoNextNL of the Government of the Netherlands
The catalytic properties of Pd alloy thin films are enhanced by a thin sputtered PTFE coating, resulting in profound improvements in hydrogen adsorption and desorption in Pd-based and Pd-catalyzed hydrogen sensors and hydrogen storage materials. The remarkably enhanced catalytic performance is attributed to chemical modifications of the catalyst surface by the sputtered PTFE leading to a possible change in the binding strength of the intermediate species involved in the hydrogen sorption process.
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