期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 52, 页码 14438-14442出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408453
关键词
donor-acceptor systems; host-guest systems; metal-organic frameworks; metal uptake; sensors
资金
- City University of Hong Kong [9667092]
- Research Grants Council of HKSAR [GRF 103413]
- NSF [0087210]
- Ohio Board of Regents [CAP-491]
- Youngstown State University
Molecular components of opposite character are often incorporated within a single system, with a rigid core and flexible side arms being a common design choice. Herein, molecule L has been designed and prepared featuring the reverse design, with rigid side arms (arylalkynyl) serving to calibrate the mobility of the flexible polyether links in the core. Crystallization of this molecule with Pb-II ions led to a dynamic metal-organic framework (MOF) system that not only exhibits dramatic, reversible single-crystal-to-single-crystal transformations, but combines distinct donor and acceptor characteristics, allowing for substantial uptake of PdCl2 and colorimetric sensing of H2S in water.
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