期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 7, 页码 1921-1927出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307500
关键词
hydrogels; nanofibers; noncovalent interactions; self-assembly; supramolecular chemistry
资金
- National Science Council of the Republic of China, Taiwan [NSC 100-2113M-009-015-MY2]
- National Chiao Tung University
- Ministry of Education, Taiwan, R.O.C.
A new system for the incorporation of a phenyl/perfluorophenyl pair in the structure of a peptide hydrogelator was developed. The strategy is based on the idea that the integration of an end-capped perfluorophenyl group and a phenylalanine with a phenyl moiety in the side chain forms an intramolecular phenyl/perfluorophenyl pair, which can be used to promote the formation of the supramolecular nanofibers and hydrogels. This work illustrates the importance of structure-hydrogelation relationship and provides new insights into the design of self-assembly nanobiomaterials.
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