期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 40, 页码 10678-10681出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405462
关键词
caged compounds; photochemistry; photosensitizers; singlet oxygen; zinc
资金
- TUBITAK [113T043]
- TUBITAK
A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.
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