期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 18, 页码 4667-4670出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201311029
关键词
amination; CH functionalization; copper; heterocycles; synthetic methods
资金
- Duke University
- Burroughs Wellcome Endowment
- Duke University Pharmacological Sciences Training Program
Direct amination of heteroarenes and arenes has been achieved in a one-pot CH zincation/copper-catalyzed electrophilic amination procedure. This amination method provides an efficient and rapid approach to access a diverse range of heteroaromatic and aromatic amines including those previously inaccessible using CH amination methods. The mild reaction conditions and good functional-group compatibility demonstrate its great potential for the synthesis of important and complex amines.
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