期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 8, 页码 2378-2382出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410419
关键词
ene reaction; hippolachninA; natural products; photochemistry; total synthesis
资金
- ETH Zurich
The first total synthesis of the marine polyketide (+/-)-hippolachninA has been achieved in nine linear steps and an overall yield of 9%. Rapid access to the oxacyclobutapentalene core structure was secured by strategic application of an ene cyclization.
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