期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 15, 页码 3996-4000出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201400674
关键词
building blocks; electron acceptors; low bandgap; polymers; solar cells
资金
- National Science Foundation (MRSEC program) [DMR 1121053]
- Mitsubishi Chemical Company (Mitsubishi Chemical Center for Advanced Materials)
Here we report a novel twisted monomer based on a distorted CC double bond for low bandgap conjugated copolymers. This new building block provides several unique characteristics when compared to classical planar systems such as high solubility, electron accepting ability, and isomeric tunability. The resulting copolymers exhibit broad absorption spanning both visible and near-infrared regions leading to promising solar cell performance.
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