期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 21, 页码 5453-5457出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402556
关键词
anions; boroles; boron; Lewis bases; radicals
资金
- Deutsche Forschungsgemeinschaft
Despite the synthesis of a boryl anion by Yamashita etal. in 2006, compounds that show boron-centered nucleophilicity are still rare and sought-after synthetic goals. A number of such boryl anions have since been prepared, two of which were reported to react with methyl iodide in apparent nucleophilic substitution reactions. One of these, a borolyl anion based on the borole framework, has now been found to display single-electron-transfer (SET) reactivity in its reaction with triorganotetrel halides, which was confirmed by the isolation of the first neutral borole-based radical. The radical was characterized by elemental analysis, single-crystal X-ray crystallography, and EPR spectroscopy, and has implications for the understanding of boron-based nucleophilic behavior and the emergent role of boron radicals in synthesis. This radical reactivity was also exploited in the synthesis of compounds with rare BSn and BPb bonds, the latter of which was the first isolated and structurally characterized compound with a noncluster BPb bond.
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