期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 40, 页码 10658-10662出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404729
关键词
asymmetric catalysis; gold catalysis; micellar catalysis; surfactants
资金
- NIH [GM86485]
- Center for Scientific Computing at the CNSI
- MRL [NSF MRSEC] [DMR-1121053]
- NSF from the National Center for Supercomputing Applications [NSF TG-CHE100123]
- MRL [NSF] [CNS-0960316]
Asymmetric gold-catalyzed hydrocarboxylations are reported that show broad substrate scope. The hydrophobic effect associated with in situ-formed aqueous nanomicelles gives good to excellent ee's of product lactones. In-flask product isolation, along with the recycling of the catalyst and the reaction medium, are combined to arrive at an especially environmentally friendly process.
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