期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 24, 页码 6237-6240出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403247
关键词
boranes; electron transfer; free radicals; hydrogen-atom transfer; reduction
资金
- Ministry of Science and Technology of Taiwan [NSC 101-2113-M-002-013-MY2]
- Kenda Foundation
Chemical reduction of a hydroxyphenyl-substituted borane triggers a sequential electron-and intramolecular hydrogen-atom-transfer process to afford a hydridoborate phenoxide dianion. On the other hand, hydrogen-atom abstraction of the borane leads to the isolation of a neutral borylated phenoxyl radical, which can be transformed to the corresponding benzoquinone borataalkene derivative by reduction with cobaltocene.
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