期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 18, 页码 4587-4591出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307373
关键词
boronic esters; main-group elements; solid-state phosphorescence; tellurophenes
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation
- Alberta Innovates-Technologies Futures (New Faculty Award)
- Canada School for Energy and the Environment
- Alexander von Humboldt foundation
The synthesis of the first examples of tellurophenes exhibiting phosphorescence in the solid state and under ambient conditions (room temperature and in air) is reported. Each of these main-group-element-based emitters feature pinacolboronates (BPin) as ring-appended side groups. The nature of the luminescence observed was also investigated using computational methods.
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