期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 38, 页码 10090-10094出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404833
关键词
arenes; carbonylation; palladium; reaction mechanisms; synthetic methods
资金
- state of Mecklenburg-Vorpommern
- Bundesministerium fur Bildung und Forschung (BMBF)
Carbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium-catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields.
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