期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 48, 页码 13049-13053出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405511
关键词
allylic alcohols; asymmetric amination; chiral phosphoric acids; palladium; phosphoramidite ligands
资金
- State of Mecklenburg-Western Pomerania
- BMBF
- DFG
Cooperative catalysis by [Pd(dba)(2)] and the chiral phosphoric acid BA1 in combination with the phosphoramidite ligand L8 enabled the efficient enantioselective amination of racemic allylic alcohols with a variety of functionalized amines. This catalytic protocol is highly regio- and stereo-selective (up to e.r. 96: 4) and furnishes valuable chiral amines in almost quantitative yield.
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