期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 38, 页码 10228-10231出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201400560
关键词
C-H activation; olefination; oxidative Heck reaction; photoredox catalysis; rhodium catalysis
资金
- European Research Council under the European Union [617044]
- European Research Council (ERC) [617044] Funding Source: European Research Council (ERC)
Direct, oxidative metal-catalyzed C-H functionalizations of arenes are important in synthetic organic chemistry. Often, (over-) stoichoimetric amounts of organic or inorganic oxidants have to be used in these reactions. The combination of rhodium and photoredox catalysis with visible light allows the direct C-H olefination of arenes. Small amounts (1 mol%) of a photoredox catalyst resulted in the efficient C-H functionalization of a broad range of substrates under mild conditions.
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