期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 33, 页码 8770-8773出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404909
关键词
disulfonimides; estrone; organocatalysis; torgov cyclization; total synthesis
资金
- Max-Planck-Society
- European Research Council
,An asymmetric Torgov cyclization, catalyzed by a novel, highly Bronsted acidic dinitro-substituted disulfonimide, is described. The reaction delivers the Torgov diene and various analogues with excellent yields and enantioselectivity. This method was applied in a very short synthesis of (+)-estrone.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据