期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 12, 页码 3227-3231出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310530
关键词
alkynes; carbocycles; chirality; copper; cycloisomerization
资金
- Aix-Marseille Universite
- CNRS
- ANR (JCJC MOCER2)
- Region Paca
An original synthesis of chiral benzofulvenes triggered by organocopper reagents is reported. These enantiopure products are available through a highly chemo-, regio-, diastereo-, and enantioselective bis(alkylating) cycloisomerization process. A double chirality transfer (central-to-axial-to-central) is observed.
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