期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 49, 页码 13510-13513出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201408652
关键词
ligand effects; palladium; self-assembly; self-sorting
资金
- ACCEL
- Japan Science and Technology Agency (JST)
- KAKENHI
- MEXT [24685010, 25102007]
- Grants-in-Aid for Scientific Research [24685010, 25102001, 25102007] Funding Source: KAKEN
In the self-assembly of Pd-II ions and two different, but similarly shaped, ligands (1 and 2), neither random mixing nor self-sorting of the two ligands into two unmixed structures was observed. Instead a mixed, yet sorted, Pd-12(1)(12)(2)(12) cantellated tetrahedron (and its pseudoisomer) was selectively formed, thus revealing a fine example of intramolecular self-sorting. A case study showed that a homothetic ratio of >2 is necessary to observe cantellated tetrahedra.
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