期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 44, 页码 11921-11925出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407000
关键词
alkenes; boron; cross-coupling; palladium; synthetic methods
资金
- National Basic Research Program of China (973 Program) [2012CB821600]
- Natural Science Foundation of China [21272010, 21332002]
Palladium-catalyzed cross-coupling reactions of 1,1-diboronates with vinyl bromides and dibromoalkenes were found to afford 1,4-dienes and allenes, respectively. These reactions utilize the high reactivities of both 1,1-diboronates and allylboron intermediates generated in the initial coupling.
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