期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 31, 页码 8184-8189出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201402853
关键词
asymmetric synthesis; desymmetrization; dienamines; intramolecular Diels-Alder reactions; organocatalysis
资金
- Spanish Government [CTQ-2009-09431, CTQ-2012-12168, CTQ-2012-37420-C02-02]
The asymmetric synthesis of tricyclic compounds by the desymmetrization of cyclohexadienones is presented. The reaction tolerated a large variety of substituents at different positions of the cyclohexadienone, and heterocyclic rings of different sizes were accessible. Density functional theory calculations showed that the reaction proceeds through an asynchronous [4+2] cycloaddition.
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