期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 39, 页码 10340-10344出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201404935
关键词
collagen; PPII helix; proline; ring pucker; stereoelectronic effects
资金
- NCCR NANO
- Bachem
- SSCI fellowship
(4S)-Aminoproline is introduced as a pH-sensitive probe for tuning the conformational properties of peptides and proteins. The pH-triggered flip of the ring puckering and the formation/release of a transannular H bond were used to switch the formation of collagen triple helices on and off reversibly.
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