期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 18, 页码 4592-4596出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307656
关键词
host-guest systems; metal-organic frameworks; structural rearrangement; xylenes
资金
- EPSRC [EP/H000925]
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
- EPSRC [EP/H000925/1] Funding Source: UKRI
A flexible metal-organic framework selectively sorbs para- (pX) over meta-xylene (mX) by synergic restructuring around pX coupled with generation of unused void space upon mX loading. The nature of the structural change suggests more generally that flexible structures which are initially mismatched in terms of fit and capacity to the preferred guest are strong candidates for effective molecular separations.
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