期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 9, 页码 2473-2476出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310676
关键词
decarboxylative coupling; natural products; palladium; resveratrol; total synthesis
资金
- Fonds der Chemischen Industrie
Controlled access to resveratrol-based natural products is offered by a novel, modular concept. A common building block readily available on a large scale serves as the starting material for the introduction of structurally important aryl groups by a Pd-catalyzed decarboxylative arylation and an oxidative Heck reaction with good yields and high stereoselectivity. The modular approach is convincingly documented by the successful synthesis of three racemic resveratrol-based natural products (quadrangularin A, ampelopsin D, and pallidol).
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